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Michael Hill headshot
Fletcher Jones Foundation Professor of Chemistry
B.A., Macalester College; Ph.D., University of Minnesota
Appointed In
1994
Office
Norris Hall of Chemistry 206

Professor Hill teaches general chemistry, inorganic chemistry, and organometallic chemistry.

Professor Hill’s Google-Scholar profile is linked

His research areas include the electrochemistry and photochemistry of transition-metal complexes, activation of small molecules via transition-metal catalysis, and bioinorganic chemistry.

Publications List:  Undergraduate author

108. “Electrochemical Lipolysis Induces Adipocyte Death and Fat Necrosis: In vivo Pilot Study in Pigs.” Tiffany T. Pham, Andrew E. Heidari, Ellen M. Hong , Earl Steward, Yueqiao Qu, Lily Y. Chen , Brandyn S. Dunn, Soo hong Seo, Adeela Syed, Katelyn K. Dilley , Lauren Lee, Dana M. Hutchison, Kyle Hansen, Urja Patel, Sehwan Kim, Michael G. Hill, Brian J.F. Wong Plastic and Reconstructive Surgery 2023 , 151 , in press.

107. “Electrochemical Cornea Reshaping for Refractive Vision Correction” Anna M. Stokolosa , Jack Thomas-Colwell , Katelyn K. Dilley , Yueqiao Qu, Charlotte Cullip , Andrew E. Heidari, Nathalie Kerrigen , Kellie Hsu , Michelle Huang , Jack Leonard , Karthik R. Prasad, Brian J.F. Wong, Michael G. Hill ACS Biomaterials Science & Engineering 2023 , 9 , 595-600. 

106. “ In vivo Electrochemical Lipolysis of Fat in a Yucatan Pig Model” Carmen K. Chan, Asher Park, Dana M. Hutchison, Urja Patel , Ellen Hong , Earl Steward, Katelyn K. Dilley , Sehwan Kim, Michael G. Hill, Joon S. You, Brian J.F. Wong. Lasers in Surgery and Medicine 2023 , 55 , 135-145.

105. “Tuning Cobalt(II) Phosphine Complexes to be Axially Ambivalent” Jack Thomas- Colwell , Arvin Sookesian , Daniel A. Kurtz, Jeremy Kallick , Lawrence Henling, Troy Stitch, Michael G. Hill, Bryan M. Hunter Inorganic Chemistry 2022 , 61 , 12625-12634.

104. “Electrochemical Treatment of Human Keloid Tissue” Asher Park, Dana Hutchison, Akarsh Lai, Amanda Durkin, Kristina Shrestha, Allison C. Hu, Michael G. Hill, Brian J.F. Wong Lasers in Surgery and Medicine 2022 , 54 , S58.

103. “Potential-Driven Electrochemical Clearing of Alkaline Corneal Injuries” Katelyn K. Dilley , Pamela A. Borden , Yueqiao Qu, Andrew E. Heidari, Karthik R. Prasaad, Yan Li, Zhongping Chen, Chung-Ho Sun, Sehwan Kim, Michael G. Hill, Brian J.F. Wong Investigative Ophthalmology and Visual Science 2022 , 11 , 32.

102. “Exploring Feedback-Controlled versus Open-Ciucuit Electrochemical Lipolysis in ex-vivo and in-  vivo Porcine Fat: A Feasibility Study” Andrew E. Heidari, Ellen M. Hong, Tiffany T. Pham, Earl   Steward, Lily Y. Chen, Yueqiao Qu, Brandon Dunn, Amir Hakimi, Adeela Syed, Sehwan Kim,         Michael G. Hill, Joon You, Brian J.F. Wong Lasers in Surgery and Medicine 2022, 54, 157-169.        

101. “A Cobalt Complex in Five Oxidation States” Daniel A. Kurtz, Jibo Zhang, Arvin Sookezian , Jeremy Kallick , Michael G. Hill,* Bryan M. Hunter* Inorganic Chemistry 2021 , 60 , 17445.

100. “DNA Electrochemistry: Charge-Transport Pathways through DNA Films on Gold” Adela Nano, Ariel L. Furst,* Michael G. Hill,* Jacqueline K. Barton* Journal of the American Chemical Society 2021 , 143 , 11631-11640.

99. “Electrochemical Degradation and Saponification of Porcine Adipose Tissue” Tiffany T. Pham, Anna Stokolosa , Pamela Borden , Kyle Hansen, Ellen Hong , Tatiana B. Karsieva, Ryan Sivoraphonh, Wesley, J. Moy, Lauren Lee, Eun Hee Kim, Chung-Ho Sun, Wangcun Jia, Ji-Hun Mo, Sehwan Kim, Michael G. Hill,* Brian J.F. Wong* Scientific Reports 2020 , 10 , 20745.

98. “The Biophysical Effects of Localized Electrochemical Therapy on Porcine Skin” Tiffany T. Pham, Ellen M. Hong , Wesley J. Moy, Jiayi Zhao, Allison C. Hu, Christian H. Barnes, Pamela A. Borden , Ryan Sivoraphonh, Tatiana B. Krasieva, Lauren H. Lee, Andrew E. Heidari, Eun Hee Kim, Sang Hyun Nam, Wangcun Jia, Ji-Hum Mo, Sehwan Kim, Michael G. Hill, Brian J.F. Wong Journal of Dermatological Science 2020 , 97 , 179-186.

97. “Toward Multimarker and Functional Assays from Crude Cell Lysates: Controlling Spacing and Signal Amplification in DNA-CT-Based Bioelectrochemical Devices.” Ariel L. Furst, Natalie Muren, Michael G. Hill Current Opinion in Electrochemistry 2019 , 14 , 104 - 111.

96. “Trapping an Iron(VI) Water-Splitting Intermediate in Nonaqueous Media” Bryan M. Hunter, Niklas B. Thompson, Astrid M. Muller, George R. Rossman, Michael G. Hill, Jay R. Winkler, Harry B. Gray Joule 2018 , 2 , 747 – 763. 

95. “Electrochemical and Structural Characterization of Azotobacter vinelandii Flavodoxin II” Helen M. Segal, Thomas Spatzal, Michael G. Hill, Andrew K. Udit, Douglas C. Rees Protein Science 2017 , 26 , 1983 - 1993. 

94. “Two-Electrode Platforms for Protein Biosensing based on Charge Transport through the DNA Double Helix” Ariel L. Furst, Michael G. Hill,* Jacqueline K. Barton,* in “Electroanalytical Chemistry: A Series of Advances, Vol. 27” A. J. Bard and C. Zoski, eds. CRC Press, New York, New York, 2017. 

93. “Helix-Dependent Spin Filtering through DNA” Theodore J. Zwang, Sylvia Hurlimann , Michael G. Hill*, Jacqueline K. Barton* Journal of the American Chemical Society 2016 , 138, 15554.  

92. “Reduced and Superreduced Diplatinum Complexes” Tania Darnton, Bryan M. Hunter, Michael G. Hill, Zalis Stanislav, Antonin Vlcek, Harry B. Gray Journal of the American Chemical Society 2016 , 138 , 5699. 

91. “Potential-Driven Electromechanical Reshaping of Cartilage” Bryan M. Hunter, Jeremy Kallick, Maya Herzig, Jessica Kissel, Cyrus Manuel , Dmitri Profesenko, Brian J.F. Wong*, Michael G. Hill* Angewandte Chemie International Edition 2016 , 128 , 5587. 

90. “Heterogeneous Catalysis for Azide-Alkyne Bioconjugation in Solution via Spin Column: Attachment of Dyes and Saccharides to Peptides and DNA.” Jeremy Kallick , Sarah Harris , Andrew K. Udit,* Michael G. Hill* BioTechniques 2015 , 59 , 329. 

89. “Electrochemical Activation of Cytochrome P450.” Andrew K. Udit, Michael G. Hill, Harry B. Gray, in “Electrochemical Processes in Biological Systems.” A. Lewenstam and L. Gorton, eds, Wiley, Hoboken, New Jersey, 2015.

88. “A Multiplexed, Two-Electrode Platform for Biosensing Based on DNA Charge Transport” Ariel L. Furst, Michael G. Hill,* Jacqueline K. Barton* Langmuir 2015 , 31 , 6554. 

87. “Label-Free Electrochemical Detection of Human Methyltransferase from Tumors” Ariel L. Furst, Natalie B. Muren, Michael G. Hill,* Jacqueline K. Barton* Proceedings of the National Academy of Sciences, USA 2014 , 111 , 14985.  

86. “Electrocatalysis in DNA Sensors.” Ariel L. Furst, Michael G. Hill,* Jacqueline K. Barton* Polyhedron 2014 , 84 , 150. 

85. “Electrochemical Patterning and Detection of DNA Arrays on a Two-Electrode Platform.” Ariel Furst, Sally Landefeld , Michael G. Hill,* Jacqueline K. Barton* Journal of the American Chemical Society 2013 , 135 , 19099.  

84. “Low-Density DNA Monolayers for Enhanced Protein Detection.” Ariel Furst, Michael G. Hill*, Jacqueline K. Barton* Langmuir 2013 , 29 , 16141. 

83. “Electron Flow through Nitrotyrosinate in Pseudomonas aeruginosa Azurin.” Jeffrey J. Warren, Nadia Herrera , Michael G. Hill, Jay R. Winkler,* Harry B. Gray* Journal of the American Chemical Society 2013 , 135 , 11151. 

82. “Bioelectrocatalysis with P450 Cytochromes.” Andrew K. Udit, Michael G. Hill, in “New Developments in Electrochemistry Research.” N. S. Gotsiridze-Columbus, ed., Nova Science, Hauppauge, New York, 2013.

81. “Electrochemistry of Mammalian Cytochrome P450 2B4 Indicates Tunable Thermodynamic Parameters in Surfactant Films.” Katharine D. Hagen , James M. Gillan , Sang-Choul Im , Sally Landefeld , Griffin Mead , Megan Hiley , Lucy A. Waskell, Michael G. Hill,* Andrew K. Udit* Journal of Inorganic Biochemistry 2013 , 129 , 30. 

80. “M-M Bond-Stretching Energy Landscapes for M2(dimen)42+ in Solution (M = Rh, Ir; dimen = 1,8- Diisocyanomenthane).” Bryan M. Hunter , Randy Villahermosa , Christopher L. Exstrom, Michael G. Hill,* Kent R. Mann,* Harry B. Gray * Inorganic Chemistry 2012 , 51 , 6898-6905.  

79. “Using Metal Complex Reduced States to Monitor the Oxidation of DNA.” Eric D. Olmon, Michael G. Hill, Jacqueline K. Barton Inorganic Chemistry 2011 , 50 , 12034.  

78. “Electron Tunneling in Copper and Iron Proteins.” Andrew K. Udit, Michael G. Hill, Jay R. Winkler, Harry B. Gray. Bulletin of Japan Society of Coordination Chemistry 2011 , 57 , 2. 

77. “Characterizing the Deformational Isomers of Bimetallic Ir2(dimen)42+ (dimen = 1,8-diisocyano-p- menthane) with Vibrational Wavepacket Dynamics.” Robert Hartsock, Wenkai Zhang, Michael G. Hill, Bridgett Sabat, Kelly Gaffney Journal of Physical Chemistry A   2011 , 115 , 2920. 

76. “Electron-Transfer Rates Govern Product Distribution of P450-Catalyzed Dioxygen Reduction and C-H Bond Oxidation.” Clairisse van der Feltz , Rose Bustos , Andrew Star , Peter Goldman , Kevork Hindoyan , Bryan M. Hunter , Aram Nersissian,* Andrew K. Udit,* Michael G. Hill* Journal of Inorganic Biochemistry 2011 , 105 , 1350. 

75. “Two-Probe SECM Detection of DNA Ď€-Stack Lesions” William J. Hammond , Justin Arndt , Katarzyna U. Slowinska, Christopher Jackson , Hayden A. Burgoyne , Michael G. Hill,* Krzysztof Slowinski.* Electrochemical Society Transactions 2009 , 16 , 55. 

74. “Scanning Electrochemical Microscopy of Nile Blue Modified DNA Monolayers.” Alon Gorodetscky, William J. Hammond , Jacqueline K. Barton,* Michael G. Hill,* Krzysztof Slowinski* Langmuir 2008 , 24 , 14282. 

73. “Differential Ionic Permeation of DNA-Modified Electrodes.” Donato M. Ceres, Haley D. Hill , Andrew K. Udit, Michael G. Hill,* Jacqueline K. Barton* Journal of Physical Chemistry B 2007 , 111 , 663. 

72. “Sodium Dodecyl Sulfate-Promoted Electrochemistry of Cytochrome P450 BM3” Andrew K. Udit, Michael G. Hill,* Harry B. Gray* Langmuir 2006 , 22 , 10854. 

71. “Electrochemical and Spectroscopic Investigations of Cytochrome P450 BM3-Surfactant Film Assemblies.” Andrew K. Udit, Katharine D. Hagen , James M. Gillan , Peter Goldman , Andrew Star , Harry B. Gray, Michael G. Hill Journal of the American Chemical Society 2006 , 128 , 10320.  

70. “Electrochemical Generation of a High-Valent State of Cytochrome P450” Andrew K. Udit, Michael G. Hill,* Harry B. Gray* Journal of Inorganic Biochemistry 2006 , 100 , 519. 

69. “Redox Couples in Inducible Nitric Oxide Synthase.” Andrew K. Udit, Wendy Belliston-Bittner, Edith C. Glazer, Yen Hoang Le Nguyen, James M. Gillan , Michael G. Hill,* Michael A. Marletta,* David B. Goodin,* Harry B. Gray* Journal of the American Chemical Society 2005 , 127 , 11212.

68. “Protein-Surfactant Film Voltammetry of Cytochrome P450 BM3 and its Mutant 1-12G.” Andrew K. Udit, Nareen Hindoyan , Michael G. Hill,* Frances H. Arnold,* Harry B. Gray* Inorganic Chemistry 2005 , 44 , 4109. 

67. “Linker-Dependent Control of Electron Transfer Rates in DNA Monolayers on Gold.” T. Gregory Drummond, Michael G. Hill,* Jacqueline K. Barton* Journal of the American Chemical Society 2004 , 126 , 15010.  

66. “Carboxylic Acid-Terminated Alkanethiol SAMs on Gold Bead Electrodes as a Nonphysiological Redox Partner for Cytochrome c.” Katsumi Niki, Michael G. Hill, Harry B. Gray, in Historical Perspectives on the Evolution of Electrochemical Tools, Leddy, J.; Birss, V.; Vanysek, P., Eds. The Electrochemical Society, Inc., Pennington, New Jersey, 2004. 

65. “Expression of the Truncated Thermus Thermophilus Cytochrome c552 Gene in Escherichia coli: Characterization of the Malformed, Recombinant Cytochrome rC552 and its Conversion to a Formylated Heme Derivative (p572).” James A. Fee,* Thomas R. Todaro, Eugene Luna, Donita Sanders, Laura Hunsicker-Wang, Kirti M. Patel, Kara L. Bren, Ester Gomez-Moran , Michael G. Hill, Jingyuan Ai, Thomas M. Loehr, Pamela A. Williams, C. David Stout, Duncan McRee, and Andrzej Pastuszyn. Biochemistry 2004 , 43 , 12161. 

64. “Electrochemistry at the DNA/Electrode Interface: New Approaches to Nucleic Acids Biosensing.” Michael G. Hill, Shana O. Kelley, in Frontiers in Electrochemistry, Ulstrup, J.; Hammerich, O., Eds. Kluwer Academic Publishers, Copenhagen, Denmark, 2004 

63. “Reduction of Dioxygen Catalyzed by Pyrene-Wired Heme Domain Cytochrome P450 BM3 Electrodes.” Andrew K. Udit, Michael G. Hill,* V. Garrett Bittner, Francis H. Arnold,* Harry B. Gray* Journal of the American Chemical Society 2004 , 126 , 10218. 

62. “Electrochemical DNA Sensors.” T. Greg Drummond, Michael G. Hill,* Jacqueline K. Barton* Nature , Biotechnology 2003 , 21 , 1192. 

61. “Reduction of Ferricyanide by Methylene Blue at a DNA-Modified Rotated Disk Electrode.” Vipin Bhagat , Migran Nersissian , Elizabeth R. Boon, Weidong Wang, Michael G. Hill,* Jacqueline K. Barton* Langmuir 2003 , 19 , 9255 . 

60. “Intercalative Binding as a Determinant for Charge Transport through the Double Helix.” Elizabeth R. Boon, Nicole M. Jackson , Matthew Wightman , Michael G. Hill,* Jacqueline K. Barton* Journal of Physical Chemistry B 2003 , 107 , 11805. 

59. “Engineering the Cytochrome c Electron Entry Site.” Katsumi Niki, W. Reef Hardy, Michael G. Hill,* H. Li, James R. Sprinkle, Emanuel Margoliash, N. Nakamura, H. Ohno, Ryutaro Tanimura , Harry B. Gray* Journal of Physical Chemistry B 2003 , 107 , 9947.

58. “Spectroscopic Investigation of Stellacyanin Mutants: Axial Ligand Interactions at the Blue Copper Site.” Serena DeBeer George, Lipika Basumallick, Robert K. Szilagyi, David W. Randall, Michael G. Hill, Aram M. Nersissian, Joan S. Valentine, Britt Hedman, Keith O Hodgson, Edward I. Soloman Journal of the American Chemical Society 2003 , 125 , 11314.

57. “Gold Electrodes Wired for Coupling with Deeply Buried Active Sites in Redox Enzymes.” Corinna R. Hess, Greg A. Juda, David M. Dooley, Ricky N. Amii , Michael G. Hill,* Jay R. Winkler,* Harry B. Gray* Journal of the American Chemical Society 2003 , 125 , 7156.

56. “Electrochemical Microsensors for DNA Mutation Detection” Xing Yang, Chunnian Shi, R. Erik Holmlin, Shana O. Kelley, Michael G. Hill, Donald M. Crothers

55. “Active Carboxylic Acid-Terminated Alkanethiol SAMs on Gold Bead Electrodes for Immobilization of Cytochromes c.” Ryutaro Tanimura , Michael G. Hill,* Emanuel Margoliash, Katsumi Niki,* Hiroyuki Ohno, Harry B. Gray* Electrochemical and Solid-state Letters 2002 , 5 , E67. 

54. “Charge Transport through a Molecular π-Stack: Double Helical DNA.” Christopher R. Treadway, Michael G. Hill,* Jacqueline K. Barton* Chemical Physics 2002 , 283 , 409.

53. “Synthesis and Spectroelectrochemistry of Ir(bpy)(phen)(phi)3+, a Tris(heteroleptic) Iridium(III) Metallointercalator.” Christine Stinner, Matthew D. Wightman , Shana O. Kelley, Michael G. Hill,* Jacqueline K. Barton* Inorganic Chemistry 2001 , 40 , 5245.

  1. “Evidence for Spontaneous Formation of a Mono-Acetyl-Deuterohemin Containing Cytochrome c(572) (p572) from Purified, Recombinant Thermus thermophilus Cytochrome c(552) Synthesized in the Cytoplasm of Escherichia coli: Characterization and Identification of Pigment 572.” James A. Fee, Duncan McRee, Andrzej Pastuszyn, Kara L. Bren, Thomas M. Loehr, Michael G. Hill Journal of Inorganic Biochemistry 2001 , 86 , 215.

51. “Characterization of Methionine 160 Axial Ligand Mutants from a Soluble CuA Domain from Cytochrome ba3 of Thermus Thermophilus.” Claire E. Sluttter, Siddarth Bardhan, Angel J. DiBilio, Chad Immoos , Michael G. Hill, I. Gromov, B. Epel, D. Goldfarb, I. Pecht, Harry B. Gray*, John H. Richards*   Journal of Inorganic Biochemistry 2001 , 86 , 435.

50. “Morphology of 15-mer Duplexes Tethered to Au(111) Probed Using Scanning Probe Microscopy.” Mui Sam , Elizabeth M. Boon, Jacqueline K. Barton,* Michael G. Hill,* Eileen M. Spain* Langmuir 2001 , 17 , 5727.

49. “Total Synthesis of Heme Proteins by Native Chemical Ligation Using a Removable Auxiliary.” Donald W. Low, Michael G. Hill, Michael R. Carrasco, Stephen B. H. Kent, Paolo Botti Proceedings of the National Academy of Sciences, USA 2001 , 98 , 6554.

48. “Electrochemistry at DNA-Modified Surfaces: New Probes for Charge Transport through the Double Helix.” Nicole M. Jackson , Michael G. Hill Current Opinion in Chemical Biology 2001 , 5 , 209.

47. “Integrity of Thermus Thermophilus Cytochrome c552 Synthesized by Escherichia Coli Cells Expressing the Host-Specific Cytochrome c Maturation Genes, ccmABCDEFG: Biochemical, Spectral and Structural Characterization of the Recombinant Protein.” James A. Fee,* Ying Chen, Thomas R. Todaro, Kara L. Bren, Kirti M. Patel, Michael G. Hill, Ester Gomez-Moran , Thomas M. Loehr, Jingyuan Ai, Linda Thorny-Meyer, Pamela A. Williams, Enrico Stura, Vandana Sridhar, Duncan E. McRee. Protein Science 2000 , 9 , 2074.

46. “Mutation Detection by Electrocatalysis at DNA-Modified Electrodes.” Elizabeth M. Boon, Donato M. Ceres , Thomas G. Drummond, Michael G. Hill,* Jacqueline K. Barton* Nature, Biotechnology 2000 , 18 , 1096.

45. “Backbone-Engineered High Potential Iron Proteins: Effects of Active-Site Hydrogen Bonding on Reduction Potential.” Donald W. Low, Michael G. Hill Journal of the American Chemical Society 2000 , 122 , 11039.

44. “Synthesis, Characterization, and Electrocatalytic Oxidation of Benzyl Alcohol by a Pair of Geometric Isomers of [Ru(trpy)(4,4’-Me(2)dppi)(OH2)]2+ (where 4,4’-Me(2)dppi is 3,6-di-(4- methylpyrid-2-yl)pyridazine.” Vincent J. Catalano,* Ryan A. Heck, Anna Ohman , Michael G. Hill* Polyhedron 2000 , 19 , 1049.

43. “Single-Base Mismatch Detection Based on Charge Transport through Double-Stranded DNA.” Elizabeth M. Boon, Shana O. Kelley, Thomas G. Drummond, Michael G. Hill,* Jacqueline K. Barton* Clinical Chemistry 1999 , 45 , 2048.

42. “Characterization of a Se-Methionine Containing Soluble Domain of Subunit II from Thermus Thermophilus and Determination of the Cu-Se(Met) Distance in the CuA Center using Se and Cu K- edge EXAFS.” Ninian J. Blackburn, Martina Ralle, Ester Gomez , Michael G. Hill, Andrzej Pastuszyn, Donita Sanders, James A Fee Biochemistry 1999 , 38 , 7075. 

41. “Single-Base Mismatch Detection Based on Charge Transduction through DNA.” Shana O. Kelley, Elizabeth Boon, Jacqueline K. Barton*, Nicole M. Jackson , Michael G. Hill* Nucleic Acids Research 1999 , 27 , 4830.

40. “Long-Range Electron Transfer through DNA Films.” Shana O. Kelley, Nicole M. Jackson , Jacqueline K. Barton,* Michael G. Hill* Angewandte Chemie International Edition 1999 , 38 , 941.

39. “[Ru(bdmpp)(diimine)Cl]+ Complexes as Structural Analogs of [Ru(trpy)(diimine)Cl]+ (where bdmpp is 2,6-bis(3,5-dimethyl-N-pyrazoyl)pyridine and trpy is terpyridine).” Vincent J. Catalano,* Raif Kurtaran, Ryan A. Heck, Anna Ohman , and Michael G. Hill* Inorganica Chimica Acta. 1999 , 286 ,181. 

38. “Rational Fine-Tuning of Reduction Potentials in a Series of Chemically Synthesized Metalloproteins.” Donald W. Low* and Michael G. Hill* Journal of the American Chemical Society 1998 , 120 , 11536. 

37. “High-Potential States of Blue- and Purple-Copper Proteins.” Pernilla Wittung-Stafshede, Ester Gomez , Anna Ohman , B. Goran Karlsson, Johan Leckner, Jay R. Winkler,* Harry B. Gray,* Bo G. Malmstrom,* Michael G. Hill* Biochemica et Biophysica Acta . 1998 , 1388 , 437.

36. “Plantacyanins are Single-Domain Proteins in Both Spinach and Arabidopsis. Comparison of Stellacyanins, Uclacyanins, and a Novel Blue Copper Protein from Arabidopsis.” Aram M. Nerissiain, L. Altschmied, Chad E. Immoos , Michael G. Hill, R. M. Nalbandyan, Greg Williams, R. G. Herrmann, Joan S. Valentine Protein Science 1998 , 7 , 1915.   

35. “Orienting DNA Helices on Gold using Applied Electric Fields.” Shana O. Kelley, Jacqueline K. Barton, Nicole M. Jackson , Aaron B. Potter , Lee D. McPherson , Michael J. Allen, Eileen M. Spain,* Michael G. Hill* Langmuir , 1998 , 14 , 6781.

34. “Reduction Potentials of Blue and Purple Copper Proteins in their Unfolded States: A Closer Look at the Protein Rack.” Pernilla Wittung-Stafshede, Michael G. Hill, Ester Gomez , Angel J. DiBilio, A. Goran Karlsson, Johan Leckner, Jay R. Winkler,* Harry B. Gray,* Bo G. Malmstrom* Journal of Biological Inorganic Chemistry 1998 , 3 , 367.

33. “Steric Modulation of Electrocatalytic Benzyl Alcohol Oxidation by [Ru(tpy)(R2dppi)(O)]2+ Complexes.” Vincent J. Catalano,* Ryan Heck, Chad E. Immoos , Anna Ohman , Michael G. Hill* Inorganic Chemistry 1998 , 37, 2150.

32. “Temperature and Isotope Effects on the Rates of Photoinduced Iridium(I)-pyridinium Electron- Transfer Reactions.” David Wiedenfeld, Max Bachrach, T. Mark McCleskey, Michael G. Hill, Jay R. Winkler,* Harry B. Gray* Journal of Physical Chemistry 1997 , 101 , 8823.

31. “Reorganization Energy of Blue Copper: Effects of Temperature and Driving Force on the Rates of Electron Transfer in Ruthenium- and Osmium-Modified Azurins.” Angel J. DiBilio, Michael G. Hill, Nicklas Bonander, B. Goran Karlsson, Randy Villahermosa , Bo G. Malmstrom, Jay R. Winkler,* Harry B. Gray* Journal of the American Chemical Society 1997 , 119 , 9921.

30. “Synthesis, Characterization, and Electrochemistry of Heterometallic Dendrimers.” Sudir Achar, Chad E. Immoos , Michael G. Hill,* Vincent J. Catalano* Inorganic Chemistry 1997 , 36 , 2314.

29. “Electrochemistry of Methylene Blue at a DNA-Modified Electrode.” Shana O. Kelley, Jacqueline K. Barton,* Nicole M. Jackson , Michael G. Hill* Bioconjugate Chemistry 1997 , 8 , 31. 

28. “Direct Electrochemistry of the CuA Domain of Thermus Thermophilus Cytochrome ba3” Chad E. Immoos , Claire E.Slutter, Donita Sanders, John H. Richards, James A. Fee, Michael G. Hill,* Harry B. Gray* Journal of Biological Inorganic Chemistry 1996 , 1 , 529. 

27. “Electrochemical and IR Spectroelectrochemical Studies of the Electrocatalytic Reduction of Carbon Dioxide by [Ir(dimen)4]2+ (dimen = 1,8-diisocyanomenthane). Stephen C. Cheng, Christine A. Blaine, Michael G. Hill, Kent R. Mann Inorganic Chemistry 1996 , 35 , 7783.

26. “Electron-Transfer Studies with the CuA Domain of Thermus Thermophilus Cytochrome ba3.” Claire E. Slutter, Ralf Langen, Donita Sanders, Stephen M. Lawrence, Pernilla Wittung, Angel J. Di Bilio, Michael G. Hill, James A. Fee, John H. Richards, Jay R. Winkler,* Bo G. Malmstrom* Inorganica Chimica Acta 1996 , 243 , 141.

25. "Electrochemistry of Chloro(terpyridine)platinum(II): Characterization of Dimerization Equilibria in Three Oxidation States." Michael G. Hill, James A. Bailey, Vincent M. Miskowski, Harry B. Gray Inorganic Chemistry 1996 , 35 , 4585.

24. "Solid State Bond-Stretch Isomerism in Binuclear Organometallic Complexes: X-ray Structural Characterization of Rh2(dimen)42+ and Ir2(dimen)42+ Salts (dimen = 1,8-diisocyanomenthane) with an Exceptionally Wide Range of Metal-Metal Distances and Dihedral Twist Angles" Christopher E. Exstrom, Kent R. Mann,* Vincent M. Miskowski,* Michael G. Hill,* Harry B. Gray* Inorganic Chemistry 1996 , 35 , 549.

23. "Rates of Heme Oxidation and Reduction in Ru(His33)Cytochrome c at Very High Driving Forces." Gary A. Mines, Morten J. Bjerrum, Michael G. Hill, Danilo R. Casimiro, I-Jy Chang, Jay R. Winkler,* Harry B. Gray* Journal of the American Chemical Society 1996 , 118 , 1961.

22. “Electron Transfer in Ruthenium-Modified Proteins.” Morton J. Bjerrum, Danilo R. Casimiro, I-Jy Chang, Angel J. DiBilio, Harry B. Gray,* Michael G. Hill, Ralph Langen, Gary A. Mines, Lars K. Skov, Jay R. Winkler, Debbie S. Wuttke Journal of Bioenergetics and Biomembranes 1995 , 27, 295.

21. “Tricarbonyl(1,10-phenanthroline)(imidazole)rhenium(I): a Powerful Photooxidant for Investigations of Electron Tunneling In Proteins.” William B. Connick, Angel J. DiBilio, Michael G. Hill, Jay R. Winkler,* Harry B. Gray* Inorganica Chimica Acta 1995 , 240 , 169.

20. “Electrochemical Studies of Organometallic Complexes with Tetra-n-butylammonium Tetrakis[3,5- bis(trifluoromethyl)phenyl]borate as the Electrolyte. X-Ray Crystal Structure of [C5(CF3)(CH3)4]Fe(C5H5).” Paul G. Gassman,* John R. Sowa, Jr., Michael G. Hill, Kent R. Mann Organometallics 1995 , 14 , 4879.

19. “Structures, Electronic Properties, and Oxidation-Reduction Reactivity of Halogenated Iron Porphyrins.” Mark W. Grinstaff, Michael G. Hill, Eva R. Birnbaum, William P. Schaefer, Jay A. Labinger, Harry B. Gray Inorganic Chemistry 1995 , 34 , 4896.

18. "The Electronic Spectroscopy of Chloro(terpyridine)platinum(II)." James A. Bailey, Michael G. Hill, Vincent M. Miskowski, William E. Marsh, William E. Schaefer, Harry B. Gray Inorganic Chemistry 1995 , 34 , 4591.

17. "Electrochemistry of Perhalogenated Tetraphenylporphyrins." Julia A. Hodge, Michael G. Hill, Harry B. Gray Inorganic Chemistry 1995 , 34 , 809.

16. "Infrared Spectroelectrochemistry of [Rh(TM4)2M(CO)5]22+ (TM4 = 2,5-diisocyano-2,5- dimethylhexane; M = Re, Mn): Electron-Transfer-Promoted Metal-Metal Bond Cleavage and Formation." Michael G. Hill, John P. Bullock, Timothy Wilson, Paul Bacon , Christine A. Blaine, Kent R. Mann Inorganica Chimica Acta 1994 , 226 , 61.

15. "Spectroscopy and Photophysics of Rh2(dimen)42+ (dimen = 1,8-diisocyanomenthane). Exceptional Metal-Metal Bond Shortening in the Lowest Energy Excited States." Vincent M. Miskowski, Steven R. Rice, Richard F. Dallinger, Harry B. Gray,* Michael G. Hill, Christopher E. Exstrom, Kent R. Mann* Inorganic Chemistry 1994 , 33 , 2977.

14. "Mechanism of Catalytic Oxygenation of Alkanes by Halogenated Iron Porphyrins." Mark W. Grinstaff, Michael G. Hill, Jay Labinger, Harry B. Gray Science 1994 , 264 , 1311.

13. "The Electronic Structure of Ligand-Bridged Complexes Containing the Rh23+ Core: ESR Spectroscopy, MO Calculations, and the X-Ray Structures of the Three Redox Pairs [Rh2(CO)2LL'{7-PhNC(Me)NPh}2]z (z = 0 and 1; L = L' = PPh3, P(OPh)3, L = PPh3C, L' = P(OPh)3)." David C. Boyd, Neil G. Connelly, Gabriel Garcia Herbosa, Michael G. Hill, Kent R. Mann*, Carlo Mealli, A. Guy Orpen, Karen E. Richardson, Philip H. Rieger* Inorganic Chemistry 1994 , 33 , 960.  

12. "The Spectroelectrochemical Characterization of Ir2(dimen)4+ and Ir2(dimen)4 (where dimen = 1,8-diisocyanomenthane)." Michael G. Hill, Andrew G. Sykes, Kent R. Mann Inorganic Chemistry 1993 , 32 , 783.  

11. "Photochemical Formation of Oligothiophene Cation Radicals in Acidic Solution and Nafion." Baruch Zinger, Kent R. Mann* Michael G. Hill, Larry L. Miller* Chemistry of Materials 1992 , 4 , 1106.

10. "Spectroelectrochemical Characterization of Oligothiophene Cation Radicals, Cation Radical π-Dimers, and Dications as Models for Polythiophene Polarons and Bipolarons." Michael G. Hill, Jean-Francois Penneau, Baruch Zinger, Kent R. Mann* Larry L. Miller* Chemistry of Materials 1992 , 4 , 1101.

9. "Infra-red Spectroelectrochemical Investigation of the Disproportionation of W2(µ- SBz)2(CO)8-." Michael G. Hill, Laurence D. Rosenhein, Kent R. Mann* Xi Hai Mu, Franklin A. Schultz* Inorganic Chemistry 1992 , 31 , 4108.  

8. "Electrochemistry of Langmuir Blodgett and Self-Assembled Films Built from Oligoimides." Vincent W. S. Kwan, Vince Cammarata, Larry L. Miller, Michael G. Hill, Kent R. Mann

7. "Steric Control in the Synthesis and Stereochemistry of the Asymmetric "Head-to-Head" Isomer of Binuclear [Rh2(HTP5)2(dppm)2][PF6]2 (HTP5 = diisocyano-1,1,5- triphenylpentane)." Charles A. Daws, Michael G. Hill, John P. Bullock, Kent R. Mann Inorganic Chemistry 1992 , 31 , 2948.  

6. "Electrochemical and Spectroelectrochemical Studies of an Iridium-Buckminsterfullerene Complex. Evidence for C60-Localized Reductions." Robert S. Koefod, Michael G. Hill, Kent R. Mann* Chuanjing Xu, Wenyuan Lu, John R. Shapley* .

5. "Oligothiophene Cation Radical Dimers. An Alternative to Bipolarons in Oxidized Polythiophene." Michael G. Hill, Kent R. Mann,* Larry L. Miller,* Jean-Francois Penneau.  

4. "The Electroactive Species in the Catalytic Oxidation of Cyclohexadiene to Benzene by Rh2(TM4)42+ (TM4 = 2,5-diisocyano-2,5-dimethylhexane)." Michael G. Hill, Kent R. Mann Catalysis Letters 1991 , 11 , 341.

3. "Tetrabutylammonium Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as a Non- Coordinating Electrolyte: The Reversible 1e- Oxidations of Ruthenocene, Osmocene, and Rh2(TM4)42+ (TM4 = 2,5-diisocyano-2,5-dimethylhexane)." Michael G. Hill, William Lamanna, Kent R. Mann .

2. "Thermodynamics of Multielectron Transfer: Variable-Temperature UV-vis and IR Spectroelectrochemical Studies of the Disproportionation of d7-d8 Binuclear Rhodium Complexes." Michael G. Hill, Kent R. Mann  

1. "Synthesis of Polyisocyanide Compounds via a-Metalation Reactions." Michael G. Hill, Matthew C. Comstock , Kent R. Mann Journal of Organic  Chemistry 1990 , 55 , 4950.